![Bde](https://kumkoniak.com/8.jpg)
Moreover, values measured in the past, especially before the 1970s, can be especially unreliable and have been subject to revisions on the order of 10 kcal/mol (e.g., benzene C–H bonds, from 103 kcal/mol in 1965 to the modern accepted value of 112.9(5) kcal/mol). The majority of currently known values are accurate to within ☑ or 2 kcal/mol (4–10 kJ/mol). Nevertheless, bond dissociation energy measurements are challenging and are subject to considerable error. To convert a molar BDE to the energy needed to dissociate the bond per molecule, the conversion factor 23.060 kcal/mol (96.485 kJ/mol) for each eV can be used.Ī variety of experimental techniques, including spectrometric determination of energy levels, generation of radicals by pyrolysis or photolysis, measurements of chemical kinetics and equilibrium, and various calorimetric and electrochemical methods have been used to measure bond dissociation energy values. Īs a typical example, the bond-dissociation energy for one of the C−H bonds in ethane ( C 2H 6) is defined as the standard enthalpy change of the process The enthalpy change is temperature-dependent, and the bond-dissociation energy is often defined to be the enthalpy change of the homolysis at 0 K ( absolute zero), although the enthalpy change at 298 K ( standard conditions) is also a frequently encountered parameter. It can be defined as the standard enthalpy change when A−B is cleaved by homolysis to give fragments A and B, which are usually radical species.
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The bond-dissociation energy ( BDE, D 0, or DH°) is one measure of the strength of a chemical bond A−B. Standard enthalpy change when a chemical bond is cleaved by homolysis
![Bde](https://kumkoniak.com/8.jpg)